Search | Engineering

订阅投稿

首页工程期刊工程焦点工程成就工程前沿关于我们 English

资源类型

期刊论文 420

年份

2024 1

2023 40

2022 32

2021 32

2020 28

2019 30

2018 28

2017 16

2016 25

2015 19

2014 11

2013 25

2012 16

2011 16

2010 18

2009 9

2008 21

2007 22

2006 3

2005 1

展开︾

关键词

固体氧化物燃料电池 8

固体废物 4

资源化利用 4

应力状态 3

SOFC 2

一阶分析法 2

创新 2

固体氧化物电解池 2

快速充电 2

气化 2

电解质 2

碳基燃料 2

ARMA模型 1

Arrhenius模型 1

H₂O/CO₂共电解 1

Hugoniot 1

ISO14000标准 1

LED，颜色漂移，光通量衰减，流明衰减 1

Matlab/Simulink仿真 1

展开︾

检索范围：

排序：展示方式：

Current understanding and applications of the cold sintering process

Tong Yu, Jiang Cheng, Lu Li, Benshuang Sun, Xujin Bao, Hongtao Zhang

《化学科学与工程前沿（英文）》 2019年第13卷第4期页码 654-664 doi: 10.1007/s11705-019-1832-1

摘要： In traditional ceramic processing techniques, high sintering temperature is necessary to achieve fully dense microstructures. But it can cause various problems including warpage, overfiring, element evaporation, and polymorphic transformation. To overcome these drawbacks, a novel processing technique called “cold sintering process (CSP)” has been explored by Randall et al. CSP enables densification of ceramics at ultra-low temperature (≤300°C) with the assistance of transient aqueous solution and applied pressure. In CSP, the processing conditions including aqueous solution, pressure, temperature, and sintering duration play critical roles in the densification and properties of ceramics, which will be reviewed. The review will also include the applications of CSP in solid-state rechargeable batteries. Finally, the perspectives about CSP is proposed.

关键词： cold sintering process processing variables solid-state rechargeable batteries

HTML PDF 收藏

下一代能源储存技术——固态电池

王长虹, 孙学良

《工程（英文）》 2023年第21卷第2期页码 32-35 doi: 10.1016/j.eng.2022.10.008

HTML PDF 收藏

Solubility of CO in solid-state PET measured by pressure-decay method

CHEN Miaocan, ZHAO Ling, LIU Tao, WU Jiangwei, YUAN Weikang

《化学科学与工程前沿（英文）》 2008年第2卷第2期页码 214-219 doi: 10.1007/s11705-008-0040-1

摘要： The solubility of CO in solid-state PET was measured using a pressure-decay method. In order to calculate the solubility of CO in the amorphous region of PET, the crystallinity of solid state PET dissolved in CO at different pressures and temperatures was measured by differential scanning calorimetry (DSC). The solubility increases with increasing pressure and it follows a linear relationship and obeys Henry’s law when the pressure is below 8 MPa. The effect of temperature on solubility is weak and the solubilities at different temperatures are almost the same under low pressures. At higher pressure, the solubility decreases with an increase in temperature. The solubility of CO in the amorphous region of PET at 373.15 K, 398.15 K and 423.15 K was correlated with the Sanchez-Lacombe equation of state with a maximal correlation error of 6.69%.

关键词： Sanchez-Lacombe equation solid-state PET different relationship calorimetry

HTML PDF 收藏

Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

《能源前沿（英文）》 2023年第17卷第3期页码 320-323 doi: 10.1007/s11708-023-0889-1

摘要： Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

关键词： materials systems

HTML PDF 收藏

Spent rechargeable lithium batteries in e-waste: composition and its implications

Xianlai ZENG,Jinhui LI

《环境科学与工程前沿（英文）》 2014年第8卷第5期页码 792-796 doi: 10.1007/s11783-014-0705-6

摘要： The amount of spent rechargeable lithium batteries (RLBs) is growing rapidly owing to wide application of these batteries in portable electronic devices and electric vehicles, which obliges that spent RLBs should be handled properly. Identification of spent RLBs can supply fundamental information for spent RLBs recycling. This study aimed to determine the differences of physical components and chemical compositions among various spent RLBs. All the samplings of RLBs were rigorously dismantled and measured by an inductive coupled plasma atomic emission spectrometer. The results indicate that the average of total weight of the separator, the anode and the cathode accounted for over 60% of all the RLBs. The weight ratio of valuable metals ranged from 26% to 76%, and approximately 20% of total weight was Cu and Al. Moreover, no significant differences were found among different manufacturers, applications, and electrolyte types. And regarding portable electronic devices, there is also no significant difference in the Co-Li concentration ratios in the leaching liquid of RLBs.

关键词： rechargeable lithium batteries e-waste physical components difference analysis recycling

HTML PDF 收藏

钠超离子导体型固体电解质的改性及其在钠离子电池中的应用 Article

张强强, 周权, 陆雅翔, 邵元骏, 戚钰若, 戚兴国, 钟贵明, 杨勇, 陈立泉, 胡勇胜

《工程（英文）》 2022年第8卷第1期页码 170-180 doi: 10.1016/j.eng.2021.04.028

摘要：

固体电解质的低离子电导率及固体电解质与固态电极之间较差的界面可靠性是阻碍固态钠电池（SSSB）应用的两大紧迫挑战。本文采用简单的两步固相法合成了名义成分为Na_3+2xZr_2‒xMg_xSi₂PO₁₂ 的钠（Na）超离子导体（NASICON）型固体电解质，其中在25 ℃时Na_3.3Zr_1.85Mg_0.15Si₂PO₁₂（x=0.15, NZSP-Mg_0.15)表现出了3.54 mS∙cm^‒1的最高离子电导率。通过深入研究，本文证实晶界成分在决定NASICON总离子电导率中起着至关重要的作用。此外，由于文献中缺乏关于NASICON是否能够提供足够的阳极电化学稳定性来实现高压固态钠电池的研究，我们首先使用了高压Na₃(VOPO₄)₂F (NVOPF)正极来验证其与优化后的NZSP-Mg_0.15固体电解质之间的兼容性。通过比较不同配置（低压阴极与高压阴极、液态电解质与固体电解质）电池的电化学性能，以及对循环后的NZSP-Mg_0.15进行X射线光电子能谱（XPS）评估，结果表明，NASICON固体电解质在高电压下不够稳定，这证明了研究NASICON固体电解质和高压阴极之间界面的重要性。此外，通过将NZSP-Mg_0.15 NASICON 粉末涂在聚乙烯（PE）隔膜（PE@NASICON）上，形成了2.42 A∙h 的碳|PE@NASICON|NaNi_2/9Cu_1/9Fe_1/3Mn_1/3O₂ 非水系钠离子电池，其具有出色的循环性能，在2000 周循环后容量保持率为88%，从而证明涂有NASICON型固体电解质的隔膜具有高可靠性。

关键词：固态电解质固态钠电池 NASICON 界面隔膜涂层

HTML PDF 收藏

Highly effective extraction of oil from soybean by pretreatment of solid-state fermentation with fungi

Xiaojuan NIU, Shuyi QIU, Yuangen WU, Jie YUAN, Yingying XU

《化学科学与工程前沿（英文）》 2011年第5卷第1期页码 122-125 doi: 10.1007/s11705-010-0533-6

摘要： The solid-state prefermentation by (CICC 2377) and (CICC 40536) was employed to increase the oil extraction yield from soybean. The influence of incubation time on oil yield was investigated. The maximum oil yield extracted from the substrate prefermented by for 96 h was 23%, which increased by 47.4% compared with control (15.6%). In the same fermentation conditions, the maximum oil yield extracted from substrate prefermented by was 21.6%, which increased by 38.5% compared with control (15.6%). The quality of soybean oil was not changed obviously by the pretreatment of fermentation with fungi.

关键词： soybean Aspergillus niger Aspergillus flavus solid-state fermentation extraction of oil

HTML PDF 收藏

电池安全——从锂离子电池到固态电池

禹习谦, 陈汝颂, 甘露雨, 李泓, 陈立泉

《工程（英文）》 2023年第21卷第2期页码 9-14 doi: 10.1016/j.eng.2022.06.022

HTML PDF 收藏

A fully solid-state cold thermal energy storage device for car seats using shape-memory alloys

《能源前沿（英文）》 2023年第17卷第4期页码 504-515 doi: 10.1007/s11708-022-0855-3

摘要： Thermal energy storage has been a pivotal technology to fill the gap between energy demands and energy supplies. As a solid-solid phase change material, shape-memory alloys (SMAs) have the inherent advantages of leakage free, no encapsulation, negligible volume variation, as well as superior energy storage properties such as high thermal conductivity (compared with ice and paraffin) and volumetric energy density, making them excellent thermal energy storage materials. Considering these characteristics, the design of the shape-memory alloy based the cold thermal energy storage system for precooling car seat application is introduced in this paper based on the proposed shape-memory alloy-based cold thermal energy storage cycle. The simulation results show that the minimum temperature of the metal boss under the seat reaches 26.2 °C at 9.85 s, which is reduced by 9.8 °C, and the energy storage efficiency of the device is 66%. The influence of initial temperature, elastocaloric materials, and the shape-memory alloy geometry scheme on the performance of car seat cold thermal energy storage devices is also discussed. Since SMAs are both solid-state refrigerants and thermal energy storage materials, hopefully the proposed concept can promote the development of more promising shape-memory alloy-based cold and hot thermal energy storage devices.

关键词： shape-memory alloy (SMA) elastocaloric effect (eCE) cooled seat cold thermal energy storage

HTML PDF 收藏

Study on microbial protein and the mechanism of solid-state fermentation with periodical dynamic changes

FU Xiaoguo, CHEN Hongzhang, LI Hongqiang, MA Runyu

《化学科学与工程前沿（英文）》 2007年第1卷第2期页码 113-117 doi: 10.1007/s11705-007-0021-9

摘要： The effect of different extraction and purification conditions on the microbial protein obtained from solid-state fermentation (SSF) and the effect of periodical dynamic changes of air on protein have been studied. The mechanism of solid-state fermentation with periodical dynamic changes of air is also discussed. Compared with static solid-state fermentation, periodical dynamic changes of air afford a higher protein mass; from 1 g of the fermentation microbe, 5.3 mg of the intracellular protein (an increase of 34.63%) and 9.09 mg of the extracellular protein (an increase of 17.8%) were obtained on the sixth day of fermentation. The filter paper activity and carboxymethyl cellulose activity (FPA and CMCase) of the extracellular protein are 1.739 μmol/s and 109.592 μmol/s, respectively, which represent increases of 60.1% and 21.2% over the corresponding values for static solid-state fermentation. The FPA and CMCase of the intracellular protein are 0.245 μmol/s and 6.392 μmol/s, respectively, which represent decreases of 22.2% and 38.7% over the corresponding values for static solid-state fermentation. The enzyme activity of the microbial extracellular protein in solid-state fermentation with periodical dynamic changes of air on the fifth day is nearly equal to that on the sixth day without periodical dynamic changes of air, so the period of fermentation can be shortened. The sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) experiments suggest that pulsating air pressure stimulation leads to a decrease in the amount of protein component with molecule mass of about 80400Da, and an increase in the amount of protein component with molecule mass of about 28520Da.

HTML PDF 收藏

Solid-state NMR for metal-containing zeolites: From active sites to reaction mechanism

Xingling Zhao, Jun Xu, Feng Deng

《化学科学与工程前沿（英文）》 2020年第14卷第2期页码 159-187 doi: 10.1007/s11705-019-1885-1

摘要： Metal-containing zeolite catalysts have found a wide range of applications in heterogeneous catalysis. To understand the nature of metal active sites and the reaction mechanism over such catalysts is of great importance for the establishment of structure-activity relationship. The advanced solid-state NMR (SSNMR) spectroscopy is robust in the study of zeolites and zeolite-catalyzed reactions. In this review, we summarize recent developments and applications of SSNMR for exploring the structure and property of active sites in metal-containing zeolites. Moreover, detailed information on host-guest interactions in the relevant zeolite catalysis obtained by SSNMR is also discussed. Finally, we highlight the mechanistic understanding of catalytic reactions on metal-containing zeolites based on the observation of key surface species and active intermediates.

关键词： metal-containing zeolites solid-state NMR active site host-guest interaction reaction mechanism

HTML PDF 收藏

下一代锂电池在能源化学工程方面的研究进展 Review

张学强, 赵辰孜, 黄佳琦, 张强

《工程（英文）》 2018年第4卷第6期页码 831-847 doi: 10.1016/j.eng.2018.10.008

摘要：

锂离子电池（LIB）对当今人们的生活产生了深远的影响。然而由于插层化学本质上的限制，锂离子电池的能量密度已接近理论上限，难以满足人们在多方面日益增长的储能需求，如便携式电子设备、电动汽车和大规模储能。因此，下一代锂（Li）电池正在广泛研究中。其中，采用金属锂作为负极，插层或转化型材料作为正极的下一代锂电池是最受关注的体系，因其具有高能量密度和巨大的商业化潜力。近年来，随着材料和反应机理方面研究的深入以及技术手段的进步，锂电池取得了不断的发展。本文从下一代锂电池的电解液/ 电解质的设计出发，从能源化学工程的角度梳理锂离子电池、锂硫电池和锂空电池中的关键科学问题和研究进展，并阐述下一代锂电池未来的发展方向。下一代锂电池有望促进人类文明的可持续发展。

关键词：锂离子电池锂硫电池锂空电池锂金属固态电池电池化学电解质

HTML PDF 收藏

高亮度固体激光器技术发展研究

唐晓军,王钢,刘娇,耿林,姜东升

《中国工程科学》 2020年第22卷第3期页码 49-55 doi: 10.15302/J-SSCAE-2020.03.008

摘要：

激光推进、激光传能等重大科研方向对高亮度固体激光器技术提出了重大需求，使得相关研究持续成为国际关注焦点。本文阐述了高亮度固体激光器技术的宏观需求，梳理国内外的技术研究现状并总结发展趋势，凝练技术进一步发展所面临的问题；据此完成高亮度固体激光器的关键技术分析，并结合国情提出未来发展建议。板条激光器和光纤激光器由于具有突出优点成为研究热点，在单台激光器输出功率不断提升的同时，可配合光束合成方法来实现高亮度激光输出。研究表明，应着重推动新型激光材料、高端半导体激光泵浦源、高精度封装工艺、自适应光束控制、光束合成关键器件等方面的技术攻关，尽快形成核心技术体系；科学布局以表层增益板条激光器技术为代表的、具有良好发展潜力的固体激光器技术研究课题，加强共用基础技术研究与积淀，为未来固体激光器输出亮度、转换效率、功率质量比的持续提升奠定坚实基础。

关键词：固体激光器高亮度技术路线关键技术

HTML PDF 收藏

High performance solid-state thermoelectric energy conversion via inorganic metal halide perovskites

Lifu YAN, Lingling ZHAO, Guiting YANG, Shichao LIU, Yang LIU, Shangchao LIN

《能源前沿（英文）》 2022年第16卷第4期页码 581-594 doi: 10.1007/s11708-022-0831-y

摘要： Solid-state thermoelectric energy conversion devices attract broad research interests because of their great promises in waste heat recycling, space power generation, deep water power generation, and temperature control, but the search for essential thermoelectric materials with high performance still remains a great challenge. As an emerging low cost, solution-processed thermoelectric material, inorganic metal halide perovskites CsPb(I_1–xBr_x)₃ under mechanical deformation is systematically investigated using the first-principle calculations and the Boltzmann transport theory. It is demonstrated that halogen mixing and mechanical deformation are efficient methods to tailor electronic structures and charge transport properties in CsPb(I_1–xBr_x)₃ synergistically. Halogen mixing leads to band splitting and anisotropic charge transport due to symmetry-breaking-induced intrinsic strains. Such band splitting reconstructs the band edge and can decrease the charge carrier effective mass, leading to excellent charge transport properties. Mechanical deformation can further push the orbital energies apart from each other in a more controllable manner, surpassing the impact from intrinsic strains. Both anisotropic charge transport properties andZT values are sensitive to the direction and magnitude of strain, showing a wide range of variation from 20% to 400% (with a ZT value of up to 1.85) compared with unstrained cases. The power generation efficiency of the thermoelectric device can reach as high as approximately 12% using mixed halide perovskites under tailored mechanical deformation when the heat-source is at 500 K and the cold side is maintained at 300 K, surpassing the performance of many existing bulk thermoelectric materials.

关键词： inorganic metal halide perovskites mechanical deformation thermoelectrics first-principle calculations Boltzmann transport theory

HTML PDF 收藏

Nickel nanopore arrays as promising current collectors for constructing solid-state supercapacitors with

Huaping Zhao, Long Liu, Yaoguo Fang, Ranjith Vellacheri, Yong Lei

《化学科学与工程前沿（英文）》 2018年第12卷第3期页码 339-345 doi: 10.1007/s11705-018-1699-6

摘要：

In this work, nickel nanopore arrays with a highly-oriented nanoporous structure inherited from porous alumina membranes were used as nanostructured current collectors for constructing ultrahigh rate solid-state supercapacitors. A thin layer of poly(3,4-ethylenedioxythiophene) (PEDOT) as electroactive materials was conformally coated onto nickel nanopores to form heterostructured electrodes. The as-prepared electrodes have a large specific surface area to ensure a high capacity, and the highly-oriented nanoporous structure of nickel nanopores reduces the ion transport resistance, allowing the ions in the solid-state electrolytes to quickly access the PEDOT surface during the fast charge-discharge process. As a result, the assembled solid-state supercapacitor in a symmetric configuration exhibits an ideal capacitive behavior and a superior rate capability even at an ultrahigh scan rate of 50 V·s⁻¹.

关键词： supercapacitor ultrahigh rate metallic nanopore arrays current collectors PEDOT